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    Synthesis of [Si1-xGex]136 type II clathrates (0.1<x<0.5): alloyed semiconductor cages in crystalline vs. amorphous products

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    REMRSEC-REU-2013-Poster-RAHARJ ...
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    Synthesis of [Si1-xGex]136 type ...
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    Author
    Raharjo, Taufik
    Toberer, Eric
    Koh, Carolyn A.
    Krishna, Lakshmi
    Date
    2013-08
    Keywords
    REMRSEC
    
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    URI
    https://hdl.handle.net/11124/331; http://dx.doi.org/10.25676/11124/331
    Abstract
    The unique thermal, electrical, optical, and structural properties of Group IV clathrates have brought them to the forefront of potential renewable energy opportunities. Specifically, the semiconductor capabilities of crystalline alloyed silicon-germanium clathrate are especially promising due to the tenability of these properties for photovoltaics or thermoelectrics. However, a successful crystalline clathrate has yet to be formed at all molar compositions of SiGe. Therefore, understanding the critical parameters which control the formation of a crystalline alloyed SoGe clathrate are indispensable to employing these materials for semiconductor applications.
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