MSN supported single site Pt and Pd complexes for catalytic C-H activation reactions

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dc.contributor.advisorTrewyn, Brian
dc.contributor.authorKunal, Pranaw
dc.contributor.committeememberRichards, Ryan
dc.contributor.committeememberBoyes, Stephen G.
dc.date.accessioned2007-01-03T05:36:19Z
dc.date.accessioned2022-02-09T08:51:36Z
dc.date.available2014-02-01T04:18:44Z
dc.date.available2022-02-09T08:51:36Z
dc.date.issued2013
dc.description2013 Summer.
dc.descriptionIncludes illustrations (some color).
dc.descriptionIncludes bibliographical references.
dc.description.abstractMesoporous materials have several advantages like high surface area, high pore volumes, easily controllable, and relatively uniform and narrow pore size distributions, and convenient ways of attachment of desired organic or organometallic species lead to multi use organic-inorganic hybrid materials which have been effectively utilized for various applications such as drug delivery, enzyme encapsulation, catalysis, sensors, and nanoelectronics etc. Single site Pt (II) complexes were covalently tethered on mesoporous silica nanoparticles (MSNs) using co-condensation and grafting methods and the resulting catalysts were studies for olefin hydroarylation reaction of unactivated olefins. A comprehensive study was carried out towards understanding the different structural aspects of the catalysts and catalysis. A comparison was made between heterogeneous catalysts and homogeneous catalysts reported in previous studies. Single site Pd (II) complexes were covalently tethered on mesoporous silica nanoparticles (MSNs) using co-condensation and grafting methods and the resulting catalysts were studies for allylic acetoxylation reaction of alkenes. Various novel approaches were tried to understand the various aspects of this catalysis in detail.
dc.format.mediumborn digital
dc.format.mediummasters theses
dc.identifierT 7315
dc.identifier.urihttps://hdl.handle.net/11124/79457
dc.languageEnglish
dc.language.isoeng
dc.publisherColorado School of Mines. Arthur Lakes Library
dc.relation.ispartof2010-2019 - Mines Theses & Dissertations
dc.rightsCopyright of the original work is retained by the author.
dc.rights.access6-month embargo
dc.subject.lcshMesoporous materials
dc.subject.lcshSilica
dc.subject.lcshCatalysts
dc.subject.lcshCatalysis
dc.titleMSN supported single site Pt and Pd complexes for catalytic C-H activation reactions
dc.typeText
dcterms.embargo.expires2014-02-01
dcterms.embargo.terms2014-02-01
dspace.entity.typePublication
thesis.degree.disciplineChemistry and Geochemistry
thesis.degree.grantorColorado School of Mines
thesis.degree.levelMasters
thesis.degree.nameMaster of Science (M.S.)
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MSN supported single site Pt and Pd complexes for catalytic C-H activation reactions
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