• Login
    View Item 
    •   Home
    • Theses & Dissertations
    • 2013 - Mines Theses & Dissertations
    • View Item
    •   Home
    • Theses & Dissertations
    • 2013 - Mines Theses & Dissertations
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of Mines RepositoryCommunitiesPublication DateAuthorsTitlesSubjectsThis CollectionPublication DateAuthorsTitlesSubjects

    My Account

    Login

    Mines Links

    Arthur Lakes LibraryColorado School of Mines

    Statistics

    Display Statistics

    MSN supported single site Pt and Pd complexes for catalytic C-H activation reactions

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Thumbnail
    Name:
    Kunal_mines_0052N_10262.pdf
    Size:
    4.662Mb
    Format:
    PDF
    Description:
    MSN supported single site Pt and ...
    Download
    Author
    Kunal, Pranaw
    Advisor
    Trewyn, Brian
    Date issued
    2013
    Keywords
    Mesoporous materials
    Silica
    Catalysts
    Catalysis
    
    Metadata
    Show full item record
    URI
    https://hdl.handle.net/11124/79457
    Abstract
    Mesoporous materials have several advantages like high surface area, high pore volumes, easily controllable, and relatively uniform and narrow pore size distributions, and convenient ways of attachment of desired organic or organometallic species lead to multi use organic-inorganic hybrid materials which have been effectively utilized for various applications such as drug delivery, enzyme encapsulation, catalysis, sensors, and nanoelectronics etc. Single site Pt (II) complexes were covalently tethered on mesoporous silica nanoparticles (MSNs) using co-condensation and grafting methods and the resulting catalysts were studies for olefin hydroarylation reaction of unactivated olefins. A comprehensive study was carried out towards understanding the different structural aspects of the catalysts and catalysis. A comparison was made between heterogeneous catalysts and homogeneous catalysts reported in previous studies. Single site Pd (II) complexes were covalently tethered on mesoporous silica nanoparticles (MSNs) using co-condensation and grafting methods and the resulting catalysts were studies for allylic acetoxylation reaction of alkenes. Various novel approaches were tried to understand the various aspects of this catalysis in detail.
    Rights
    Copyright of the original work is retained by the author.
    Collections
    2013 - Mines Theses & Dissertations

    entitlement

     
    DSpace software (copyright © 2002 - 2022)  DuraSpace
    Quick Guide | Contact Us
    Open Repository is a service operated by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.