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Multiscale characterization of defects in 4H-SiC high-power devices and the effect on MOSFET reliability

El Hageali, Sami A.
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Abstract
Silicon carbide (4H-SiC) has been accepted as an optimal semiconductor that can substitute for silicon for fabricating advanced power devices for high temperature, power, and frequency applications, owing to its outstanding physical properties. Despite the major progress in SiC process technology, SiC-based devices suer from bipolar degradation. As an example, SiC p-i-n diodes have previously suered from an increase in the forward voltage drop under forward conduction stress. It was discovered that the basal plane dislocations (BPDs) in epitaxial layers result in the formation of stacking faults (SFs) that can expand through a mechanism called \recombination enhanced glide mechanism" whenever the p-i-n diode is forward biased. The SFs represent regions of poor lifetime and are regions with poor conductivity modulation. Indeed, SFs not only act as recombination centers but also impede the ow of majority carriers. The occurrence of SFs must therefore be prevented, the expansion behavior needs to be understood and correlated to SiC-based device performance. For this reason, the central focus of this dissertation is to provide a full understanding of specic types of extended defects found in commercial wafers through a multiscale analysis and study the eect on 4H-SiC metal{oxide{semiconductor eld-eect transistors (MOSFETs) reliability. The rst study highlights the power of a multiscale luminescence characterization approach to studying extended defects in epitaxial 4H-SiC semiconducting materials using two complimentary techniques, photoluminescence (PL) and cathodoluminescence (CL). The BPD network generated from strain around a down-fall particle indicated the presence of dierent structures, such as Shockley-type and Frank-type SFs. Ultraviolet-PL imaging allowed for a rapid identication of the inner structure of the defect by revealing the BPD network and the presence of various SFs, and CL was used to provide better spatial and spectral information. This detailed optical analysis provides a pathway for the fundamental understanding of the impact of defects on device performance and provides a better understanding of their formation and development during epitaxial growth. In this work, an inclusion was selected as an example, but this method applies to any heterostructures or areas that show BPDs. The nature, origin and behavior under device operation of so called "trapezoidal defects" were revealed using a complete multiscale characterization study and the results were correlated with degradation of MOSFETs having this defect. The correlation between the luminescence and microscopy results allowed us to precisely identify the nature of these SFs as: Single Shockley, Extrinsic Frank type (2,3)n and, Multilayer Frank type (4,2), 8H. The optoelectronic study showed that expansion of SFs within the trapezoidal defect is greatly hampered by sessile dislocations and that trapezoidal defects are spread on multiple basal planes; Electron beam induced current (EBIC) imaging showed that dislocations within this defect act as strong sites of carrier recombination which is likely to have an impact on the on-state transfer characteristics of SiC devices. EBIC and Transmission electron microscopy (TEM) revealed that trapezoidal defects come from the substrate and propagate into the epilayer. Furthermore, device electrical measurements showed that as the percentage coverage of trapezoidal defects increases within the active area of a MOSFET device, the on-state resistance increases. Body diode stressing measurements are in agreement with the statement that expansion of SFs within the trapezoidal defect is greatly hampered by sessile dislocations which in part is benecial to body diode degradation. Indeed, the results showed that trapezoidal defects do not degrade devices as much as SFs that can freely expand. Overall, our conclusions nd that trapezoidal defects should still be considered non-killer at low percentage coverage in the active are, but eorts by substrate and epilayer manufacturers need to be made to erase their occurrence. The origin, formation mechanism and behavior of "Star-defect" under device operation were investigated. This study shows that the in-grown star-shaped defect originates in the substrate from on-axis grown boule and propagates until the epilayer/substrate interface. It has a highly strained center core, with primary arms and novel secondary dislocation arrays that were found to be emanating from the primary arms. The secondary arrays are found to be prismatic faults formed from intersection of BPDs. Star-defect has BPDs aggregate present along its core as well as at intersections between primary arms/secondary arrays. These aggregates are nucleation points of SFs expansion that propagate from multiple depths until reaching the epilayer. The total impact on device yield is critical for a single star-defect with secondary arrays as the defect spans a large wafer area (5 by 5 cm-2). A wafer having multiple star-defects will pass initial MOSFETs screening-tests making the devices available on the market but a rapid electrical degradation of the MOSFET is expected. The results presented are crucial to industrial manufacturers in order to assess device reliability. As a result of this work, SiC devices' electrical yield and the potential degradation can be sampled in real time during fabrication.
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